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韩艳春 研究员

文章来源:    发布时间:2011-03-30
  韩艳春 研究员
 
博士生导师
高分子物理
高分子薄膜与表面图案化
 
主楼412室
电话:0431-85262175
传真:0431-85262126
Email:ychan@ciac.ac.cn
教育和工作经历
高分子物理与化学国家重点实验室(长春),实验室主任(2005.4-2015.4)
高分子物理与化学国家重点实验室(长春),研究员,博士生导师(2000-至今)
美国得克萨斯大学奥斯汀分校,访问教授(2002.12-2003.01)
日本学术振兴会(JSPS)资助的日本九州大学,访问教授,(2004.11-2004.12)
美国密歇根大学,博士后,访问科学家,(1999-2000)
德国Kaiserslautern大学,洪堡奖学金,德国Martin-Luther大学Halle-Wittenberg,德国学术交流中心-王宽城奖学金(1996-1998,1998)
意大利Naples大学,访问学者(1996)
中国科学院长春应用化学研究所,高分子化学与物理博士学位(1995)
中国科学技术大学,高分子化学学士学位(1990)
学术兼职
Langmuir, 顾问编委(2008-2012)
科学通报, 编辑委员会委员(2007-2009)
Chinese Journal of Polymer Science, 编辑委员会委员(2011-2015)
化学学报,编辑委员会委员(2012-)
有机无机复合材料国家重点实验室学术委员(2011-)
中国科学院生态环境材料重点实验室学术委员会委员(2010-)
中国化学会国际事务工作委员会委员(2008-)
高分子学科委员会委员(2011-2015)
主要荣誉
国家杰出青年科学基金,结题验收特优 2000
“新世纪百千万人才工程”国家级人选(2006)
获吉林省科学技术进步一等奖1 项(2010)
吉林省杰出青年科学研究计划获得者(2001)
中国科学院长春分院优秀青年科技人才(2001)
第六届长春十大杰出青年(2004)
享受政府特殊津贴(2005)
吉林省“五一劳动奖章”(2005)
吉林省优秀专业技术人才(2005)
吉林省十佳女职工标兵(2005)
吉林省第八届青年科技奖获得者(2006)
中国科学院“优秀研究生指导教师”(2006)
中国科学院研究生院优秀教师(2006)
吉林省第二批拔尖创新人才第三层次人选(2007)
冯新德高分子奖最佳文章提名奖(2008)
第三届冯新德高分子奖 (The 3rd Feng Xinde Polymer Prize)最佳文章提名奖(2010)
吉林省第三批高级专家(2011)
研究资助
国家自然科学基金委员会面上项目、重点项目、 创新研究群体、科技部973
研究兴趣
功能高分子薄膜多层次有序结构的构筑、调控与应用
有机光电功能器件的微加工
研究领域和现状
   光电功能高分子是高分子科学与信息科学高度交叉的学科,已成为国际科学前沿和高技术竞争焦点。其研究核心是建立光电高分子、功能薄膜与光电器件的内在关联,其应用目标是平板显示、太阳能电池和电子电路等高技术领域。我们课题组研究重点集中在功能高分子薄膜多层次有序结构的构筑、调控与应用和有机光电功能器件的微加工。

   1.功能高分子薄膜多层次有序结构的构筑、调控与应用   
   围绕共轭高分子薄膜形态与电荷传输核心问题,开展如下研究:(1)控制共轭聚合物分子在溶液加工过程中的链构象和π-π 堆积方式,通过调控分子-分子相互作用和分子-界面相互作用,建立分子结构、薄膜溶液加工技术、不同层次有序结构(分子堆砌排列方式、晶界连接与取向等)间的关系。(2)利用棒杆-棒杆(rod-rod)共轭嵌段共聚物的微观相分离以及链段之间的刚性不对称性,通过结晶与相分离强弱竞争、结晶诱导有序-有序转变、优化共轭分子之间π-π相互作用等,控制共轭嵌段共聚物结晶分子取向,制备其尺寸与激子扩散长度(~10nm)相匹配的多尺度有序结构。(3)通过调控给体/受体共混体系的热力学及动力学参数,控制共轭聚合物共混物相分离的动态过程,建立具有高载流子传输特性的给体/受体纳米互穿网络形态控制方法,制备出相区尺寸小于激子的传输距离、具有较大界面和最大程度的相区有序性的微结构;(4)揭示影响共轭聚合物共混物光诱导电荷分离、载流子传输及复合的物理机制,建立分子结构-薄膜形态-光电性质的内在关联。预期将发展的形态可控、相态可调的大面积、高有序、无缺陷、具有优良形态和相态稳定性的高分子光电薄膜形态调控技术用于器件组装,并获得综合性优异的器件,为有机光电器件产业化提供薄膜技术。

凝聚态结构与性能

高分子薄膜太阳能电池异质结结构

   2.有机光电功能器件的微加工   
   光电功能高分子的薄膜微加工与纳米图案化是制备光电器件的重要环节,需要结合器件结构确定微加工工艺和加工过程。由于有机高分子发光材料易于溶液方式低成本加工的特点,近年来许多基于印刷和打印的有机发光薄膜图案化方法被研究开发,我们研究集中在:(1)喷墨打印有机发光聚合物/小分子薄膜质量调控:喷墨打印聚合物薄膜均匀性与微结构协同调控溶剂体系,制备厚度均匀的光滑无定形薄膜, 与旋涂性能相当的喷墨打印器件制备工艺。(2)图案化技术:研究微接触印刷、纳米压印、丝网印刷等技术在高分子薄膜图案化和电极加工等方面的应用,发展构筑大面积有序图案的方法和途径。

主要代表性论文
  2002年以来在Prog. Polym.Sci., Chem. Soc. Rev., Adv. Mater., J. Am. Chem. Soc., Adv. Func. Mater.等杂志上共发表相关研究论文177篇,其中SCI收录论文175 篇,包括影响因子大于3.0论文108篇。
 1. Longjian Xue, and Yanchun Han, Pattern formation by dewetting of polymer thin film,Prog. Polym. Sci.2011, 36 (2), 269-293.
 2. Longjian Xue, Jilin Zhang, Yanchun Han, Phase separation induced ordered patterns in thin polymer blend films, Prog. Polym. Sci. 2012,37, 564-594.
 3. Jilin Zhang, Yanchun Han, Active and responsive polymer surfaces, Chem. Soc. Rev.2010, 39, 676–693.
 4. Longjian Xue, Yanchun Han, Inhibition of dewetting of thin polymer films, Prog. Mater. Sci. Accepted.
 5. Zhe Wang, Jianfeng Yuan, Jian Zhang, Rubo Xing, Donghang Yan, Yanchun Han, Metal transfer printing and its application in organic field-effect transistor fabrication, Adv. Mater.2003, 15(12), 1009-1012.
 6. Zhe Wang, Jian Zhang, Rubo Xing, Jianfeng Yuan, Donghang Yan, and Yanchun Han, Micropatterning of organic semiconductor microcrystalline materials and OFET fabrication by “Hot Lift Off”, J. Am. Chem. Soc.2003, 125 (50) 12578-12579.
 7. Xiao Li, Junpeng Gao, Longjian Xue and Yanchun Han, Porous polymer film with gradient-refractive-index structure for broad-band and omnidirectional antireflection coating, Adv. Funct. Mater.2010,20, 259-265.
 8. Min Yu, Jun Lin, Zhe Wang, Jun Fu, Shubin Wang, Hongjie Zhang, and Yanchun Han, Fabrication, patterning, and optical properties of nanocrystalline YVO4:A (A= Eu3+, Dy3+, Sm3+, Er3+) phosphor films via Sol-Gel soft lithography, Chem. Mater.2002, 14(5), 2224-2231.
 9. Ziyong Cheng, Baoxiang Gao, Maolin Pang, S. W. Wang, Yanchun Han and Jun Lin, Preparation and characterization of a novel layered perovskite-type organic/inorganic hybrid material containing silica networks, Chem. Mater. 2003, 15(25), 4705-4708.
 10. Min Yu, Jun Lin, Jun Fu, H. J. Zhang, Yanchun. Han, Sol-gel synthesis and photoluminescent properties of LaPO4:A (A=Eu3+, Ce3+, Tb3+) nanocrystalline thin films, J. Mater.Chem. 2003, 13, 1413–1419.
 11. Xiao Li, Longjian Xue, Yanchun Han, Broadband antireflection of block copolymer/homopolymer blends films with gradient-refractive-index structures, J. Mater. Chem. J. Mater. Chem., 2011, 21, 5817.
 12. Xiao Li, Yanchun Han, Tunable wavelength antireflective film by non-solvent-induced phase separation of amphiphilic block copolymer micelle solution, J. Mater. Chem., 2011, 21, 18024.
 13. Kai Yu, Yanchun Han, A stable PEO-tethered PDMS surface having controllable wetting property by a swelling-deswelling process, Soft. Matter2006, 2 (8), 705-709.
 14. Yuhan Wei, Binyao Li, Yanchun Han and Caiyuan Pan, Ring-shaped morphology in H-shaped block copolymer thin film, Soft Matter 2008, 4, 2507-2512.
 15. Kai Yu, Yanchun Han, Effect of block sequence and block length on the stimuli-responsive behavior of polyampholyte brushes: hydrogen bonding and electrostatic interaction as the driving force for surface rearrangement, Soft Matter 2009, 5, 759-768.
 16. Wei Xiong, Hanfu Wang and Yanchun Han, Oxidation induced self-assembly transformation of dendron-b-oligoaniline-b-dendron dumbbell shape triblock oligomer, Soft Matter,2011,7,8516-8524.
 17. Jun Fu, Bin Luan, Xiang Yu, Yang Cong, Jian Li, Caiyuan Pan, Yanchun Han, Yuming Yang, Binyao Li, Self-assembly of crystalline-coil diblock copolymer in solvents with varying selectivity: from spinodal-like aggregates to spheres, cylinders, and lamellae, Macromolecules2004, 37(3), 976-986.
 18. Jun Fu, Yang Cong, Jian Li, Bin Luan, Caiyuan Pan, Yuming Yang, Binyao Li, Yanchun Han, Hole nucleation and growth induced by crystallization and microphase separation of thin semicrystalline diblock copolymer films, Macromolecules 2004, 37(18), 6918-6925.
 19. Yu Xuan, Juan Peng, Liang Cui, Hanfu Wang, Binyao Li, Yanchun Han, Morphology development of ultrathin symmetric diblock copolymer film via solvent vapor treatment, Macromolecules 2004, 37(19), 7301-7307.
 20. Jun Fu, Bin Luan, Caiyuan Pan, Binyao Li, Yanchun Han, Early stage interplay of microphase separation and crystallization in crystalline-coil poly(L-lactic acid)-block-polystyrene thin films, Macromolecules2005, 38(12), 5118-5127.
 21. Yang Cong, Binyao Li, Yanchun Han, Yugang Li, Caiyuan Pan, Self-assembly of h-shaped block copolymers, Macromolecules 2005, 38(23), 9836-9846.
 22. Weihuan Huang, Chunxia Luo, Binyao Li, and Yanchun Han, Solvent-induced crystallization of spherical micelles formed by copolymer blends, Macromolecules 2006, 39(23), 8075-8082.
 23. Weihuan Huang, Chunxia Luo, Jilin Zhang, Kai Yu, and Yanchun Han, Tethered diblock copolymer chains on platelets prepared by semicrystalline ABC triblock copolymers in toluene with trace amounts of water, Macromolecules2007, 40(22), 8022-8030.
 24. Xinhong Yu, Hua Yang, Shupeng Wu, Yanhou Geng, Yanchun Han*, Microphase separation and crystallization of all-conjugated Phenylene-Thiophene diblock Copolymers, Macromolecules, 2012, 45, 266-274.
 25. Jun Fu, Xiaoshuang Feng, Yanchun Han?, Caiyuan Pan, Yuming Yang and Binyao Li, Fabrication of a metal particle array based on a self-assembled template from a two-armed polymer, Macromol. Rapid Commun.2003, 24, 487–491.
 26. Xiang Yu, Jun Fu, Yanchun Han, Caiyuan Pan, AFM study of the self-assembly behavior of hexa-armed star polymers with a discotic triphenylene core, Macromol. Rapid Commun.2003, 24, 742–747.
 27. Jilin Zhang, Jian Li, Yanchun Han, Superhydrophobic PTFE surfaces by extension, Macromol. Rapid Commun.2004, 25(11), 1105-1108.
 28. Yu Xuan, Juan Peng, Hanfu Wang, Binyao Li, Yanchun Han, The formation of ordered nanoholes in binary, chemically similar, symmetric diblock copolymer blend films, Macromol. Rapid Commun.2004, 25(12), 1181-1185.
 29. Xiaoying Lu, Changchun Zhang, Yanchun Han, Low-density polyethylene superhydrophobic surface by control of its crystallization behaviour, Macromol. Rapid Commun.2004, 25(18), 1606-1610.
 30. Jilin Zhang, Xiaoying Lu, Weihuan Huang, Yanchun Han, Reversible superhydrophobicity to superhydrophilicity transition by extending and unloading an elastic polyamide film, Macromol. Rapid Commun.2005, 26(6), 477-480.
 31. Xiaoying Lu, Jilin Zhang, Changchun Zhang, Yanchun Han, Low-density polyethylene (LDPE) surface with a wettability gradient by tuning its microstructures, Macromol. Rapid Comm. 2005, 26(8), 637-642.
 32. Juan Peng, Yuhan Wei, Hanfu Wang, Binyao Li, Yanchun Han, Solvent induced sphere development in symmetric diblock copolymer thin films, Macromol. Rapid Commun. 2005, 26(9), 738-743.
 33. Hanfu Wang, Peng Guo, Yanchun Han, Synthesis and surface morphology of tetraaniline-block-poly(L-lactate) diblock oligorners, Macromol. Rapid Commun. 2006, 27 (1), 63-68.
 34. Xiaoying Lu, Juan Peng, Binyao Li, Changchun Zhang, Yanchun Han, A polymer composite film with reversible responsive behaviors, Macromol. Rapid. Comm. 2006, 27 (2), 136-141.
 35. Libin Liu, Xiang Gao, Yong Cong, Binyao Li, Yanchun Han, Multiple morphologies and their transformation of a polystyrene-block-poly(4-vinylpyridine) block copolymer, Macromol. Rapid Commun.2006, 27 (4), 260-265.
 36. Ping Zhang, Junpeng Gao, Binyao Li, Yanchun Han, Surface morphology evolution of a thin polymeric supramolecular film by tuning interactions, Macromol. Rapid Commun. 2006, 27 (4), 295-301.
 37. Jilin Zhang, Weihuan Huang, Yanchun Han, A composite polymer film with both superhydrophobicity and superoleophilicity, Macromol. Rapid Commun. 2006, 27 (10), 804-808.
 38. Juan Peng, Yanchun Han, Wolfgang Knoll, Dong Ha Kim, Development of nanodomain and fractal morphologies in solvent annealed block copolymer thin films, Macromol. Rapid Commun. 2007, 28 (13), 1422-1428.
 39. Yuhan Wei, Weihuan Huang, Binyao Li, Yanchun Han, Caiyuan Pan, Square lamellar structure having phase-separated microdomain in H-shaped block copolymer thin film, Macromol. Rapid Commun.2008, 29(16), 1378-1384.
 40. Ping Yang and Yanchun Han, A polymer crystallization influenced by initial orientation of cylindrical diblock copolymers in thin films, Macromol. Rapid Commun.2008, 29, 1614-1619.
 41. Chunxia Luo, Weihuan Huang, and Yanchun Han, Order-order transitions (OOTs) of C→sdG→sL→S undergoing different sdG plane in ABC triblock copolymer film induced by saturated solvent vapor, Macromol. Rapid Commun.2009, 30(7), 515-520.
 42. Hanfu Wang, Yanchun Han, Vesicles formed by oligostyrene-b-oligoaniline-b-oligostyrene triblock oligomer, Macromol .Rapid Commun.2009, 30(7),521-526.
 43. Ping Yang and Yanchun Han, Microphase separated brush on square platelets in PS-b-PEO thin film, Macromol. Rapid Comm.2009, 30, 1509-1514.
 44. Chunxia Luo, Weihuan Huang and Yanchun Han, Formation of two kinds of hexagonally arranged structure in ABC triblock copolymer film induced in strongly selective solvent vapor for two end blocks, Macromol. Rapid Commun. 2009, 30, 1917-1921.
 45. Jilin Zhang, Xinhong Yu, Ping Yang, Juan Peng, Chunxia Luo, Weihuan Huang, and Yanchun Han, Microphase separation of block copolymer thin films, Macromol. Rapid Commun. 2010, 31(7), 591-608.
 46. Kui Zhao, Zicheng Ding, Longjian Xue and Yanchun Han, Crystallization-induced phase segregation based on double-crystalline blends of poly(3-hexylthiophene) (P3HT) and polyethylene glycols (PEG), Macromol. Rapid Commun. 2010, 31(6), 532-538.
 47. Wei Xiong, Hanfu Wang, Yanchun Han, Fibrils Formed by Dendron-b-oligoaniline-b-dendron Block Co-oligomer, Macromol. Rapid Commun. 2010, 31, 1886-1891.
 48. Longjian Xue, Rubo Xing*, Yanchun Han, Facile one-step fabrication of an undercut structure by solution dewetting on a water/ice mold, J. Phys. Chem. C 2010, 114(21), 9845-9849.
 49. Xue Li, Yanchun Han*, and Lijia An*, Surface Morphology Evolution of Thin Triblock Copolymer Films during Spin-Coating Langmuir 2002, 18, 5293-5298.
 50. Junpeng Gao, Jun Fu, Cuikun Lin, Jun Lin, Yanchun Han, Xiang Yu, Caiyuan Pan, Formation and photoluminescence of silver nanoparticles stabilized by a two-armed polymer with a crown ether core, Langmuir2004, 20(22), 9775-9779.
 51. Jilin Zhang, Longjian Xue, Yanchun Han, Fabrication gradient surfaces by changing polystyrene microsphere topography, Langmuir 2005, 21(1), 5-8.
 52. Jian Li, Juan Peng, Weihuan Huang, Yang Wu, Jun Fu, Yang Cong, Longjian Xue, Yanchun Han, Ordered honeycomb-structured gold nanoparticle films with changeable pore morphology: From circle to ellipse, Langmuir2005, 21(5), 2017-2021.
 53. Jilin Zhang, Longjian Xue, Yanchun Han, Fabrication of gradient colloidal topography, Langmuir 2005, 21(13), 5667-5671.
 54. Liang Cui, Yanchun Han, Honeycomb patterns formation via polystyrene/poly2-vinylpyridine phase separation, Langmuir 2005, 21(24), 11085-11091.
 55. Liang Cui, Yu Xuan, Xue Li, Yan Ding, Binyao Li, Yanchun Han, Polymer surfaces with reversibly switchable ordered morphology, Langmuir 2005, 21(25), 11696-11703.
 56. Jian Li and Yanchun Han, Optical intensity gradient by colloidal photonic crystals with a graded thickness distribution, Langmuir 2006, 22 (4), 1885-1890.
 57. Jilin Zhang, Weihuan Huang, and Yanchun Han, Wettability of zinc oxide surfaces with controllable structures, Langmuir2006, 22 (7), 2946-2950.
 58. Juan Peng, Rubo Xing, Yang Wu, Binyao Li, Yanchun Han, Wolfgang Knoll, and Dong Ha Kim, Dewetting of thin polystyrene films under confinement, Langmuir 2007, 23 (5), 2326-2329.
 59. Jilin Zhang and Yanchun Han, Shape-gradient composite surfaces: Water droplets move uphill, Langmuir 2007, 23 (11), 6136-6141.
 60. Kai Yu, Hanfu Wang, Longjian Xue, and Yanchun Han, Stimuli-responsive polyelectrolyte block copolymer brushes synthesized from the si wafer via atom-transfer radical polymerization, Langmuir2007, 23 (3), 1443-1452.
 61. Liang Cui, Binyao Li, and Yanchun Han, Transformation from ordered islands to holes in phase-separating P2VP/PS blend films by adding triton X-100, Langmuir 2007, 23 (6), 3349-3354.
 62. Kai Yu, Hanfu Wang, and Yanchun Han, Motion of integrated CdS nanoparticles by phase separation of block copolymer brushes, Langmuir2007, 23 (17), 8957-8964.
 63. Jilin Zhang and Yanchun Han, A topography/chemical composition gradient polystyrene surface: Toward the investigation of the relationship between surface wettability and surface structure and chemical composition, Langmuir 2008, 24(3), 796-801.
 64. Jianying Wang, Yanchun Han, Tunable multi-responsive methacrylic acid based inverse opal hydrogels (MIOH) by controlling the synthesis conditions, Langmuir2009, 25 (3), 1855-1864.
 65. Longjian Xue, Yanchun Han, Autophobic dewetting of poly(methyl methacrylate) thin film on silicon wafer treated in good solvent vapor, Langmuir 2009, 25(9), 5135-5140.
 66. Ping Yang, Yanchun Han, Crystal growth transition from flat-on to edge-on induced by solvent evaporation in ultrathin films of polystyrene-b-poly(ethylene oxide), Langmuir 2009, 25(17), 9960-9968.
 67. Jilin Zhang, and Yanchun Han, “Dual-parallel-channel” shape-gradient surfaces: towards oriented and reversible movement of water droplets, Langmuir2009, 25 (24), 14195-14199.
 68. Kui Zhao, Longjian Xue, Jiangang Liu, Xiang Gao, Shupeng Wu, Yanchun Han, and Yanhou Geng, A new method to improve poly(3-hexyl thiophene) (P3HT) crystalline behavior: decreasing chains entanglement to promote order-disorder transformation in solution, Langmuir 2010, 26(1), 471-477.
 69. Benhui Hu, Longjian Xue, Ping Yang and Yanchun Han*, Variable-focus Liquid Microlenses with Adjustable 3-D Curved Housings, Langmuir 2010, 26(9), 6350-6356.
 70. Jiangang Liu, Yue Sun, Xiang Gao, Rubo Xing, Lidong Zheng, Shupeng Wu, Yanhou Geng, Yanchun Han, Oriented poly(3-hexylthiophene) nanofibril with π-π stacking growth direction by solvent directional evaporation, Langmuir,2011, 27, 4212-4219.
 71. Juan Peng, Yanchun Han, Yuming Yang, Binyao Li, Pattern formation in polymer films under the mask, Polymer2003, 44, 2379-2384.
 72. Zexin Zhang, Zhe Wang, Rubo Xing, Yanchun Han, Patterning thin polymer films by surface-directed dewetting and pattern transfer, Polymer 2003, 44, 3737–3743.
 73. Xue Li, Yanchun Han*, and Lijia An*, Inhibition of thin polystyrene film dewetting via phase separation, Polymer 2003, 44, 5833-5841.
 74. Xue Li, Yanchun Han*, Lijia An*, Surface morphology control of immiscible polymer-blend thin films, Polymer 2003, 44(26), 8155-8165.
 75. Juan Peng, Yanchun Han, Yuming Yang, Binyao Li, The influencing factors on the macroporous formation in polymer films by water droplet templating, Polymer 2004, 45(2), 447-452.
 76. Xue Li, Rubo Xing, Ying Zhang, Yanchun Han, Lijia An, Molecular weight effects on the phase morphology of PS/P4VP blend films on homogeneous SAM and heterogeneous SAM/Au substrates, Polymer 2004, 45(5), 1637-1646.
 77. Jun Fu, Yang Cong, Xiang Yu, Caiyuan Pan, Yuming Yang, Binyao Li, Yanchun Han, Ordered macroporous films from self-assembly of two-armed polymer with a crown ether core, Polymer 2004, 45(22), 7389-7394.
 78. Juan Peng, Hanfu Wang, Binyao Li, Yanchun Han, Pattern formation in a confined polymer film induced by a temperature gradient, Polymer2004, 45(23), 8013-8017.
 79. Liang Cui, Hanfu Wang, Yan Ding, Yanchun Han, Tunable ordered droplets induced by convection in phase-separating P2VP/PS blend film, Polymer2004, 45(24), 8139-8146.
 80. Yang Wu, Xiaobo Yu, Yuming Yang, Binyao Li, Yanchun Han, Studies on the reactive polyvinylidene fluoride-polyamide 6 interfaces: rheological properties and interfacial width, Polymer2005, 46(7), 2365-2371.
 81. Xiaobo Yu, Yang Wu, Binyao Li, Yanchun Han, Studies on interfacial reaction kinetics and properties at a reactive compatibilization interface, Polymer 2005, 46(10), 3337-3342.
 82. Liang Cui, Juan Peng, Yan Ding, Xue Li, Yanchun Han, Ordered porous polymer films via phase separation in humidity environment, Polymer2005, 46(14), 5334-5340.
 83. Yang Cong, Zexin Zhang, Jun Fu, Jian Li, Yanchun Han, Water-induced morphology evolution of block copolymer micellar thin films, Polymer2005, 46(14), 5377-5384.
 84. Juan Peng, Yu Xuan, Hanfu Wang, Binyao Li, Yanchun Han, Solvent vapor induced dewetting in diblock copolymer thin films, Polymer 2005, 46(15), 5767-5772.
 85. Xinhong Yu, Zhe Wang, Rubo Xing, Shifang Luan, Yanchun Han, Solvent assisted capillary force lithography, Polymer2005, 46(24), 11099-11103.
 86. Shifang Luan, Hongzhou Li, Yuxi Jia, Lijia An, Yanchun Han, Qian Xiang, Jiang Zhao, Junxing Li and Charles C. Han, Analysis of micro-failure behaviors in hybrid fiber model composites, Polymer 2006, 47(17), 6218-6225.
 87. Junpeng Gao, Ping Zhang, Jun Fu, Binyao Li, Yanchun Han, Xiang Yu, Caiyuan Pan, Surface morphology evolution of poly (styrene-block-4-vinylpyridine) (PS-b-P4VP)(H+) and poly(methyl methacrylate)-dibenzo-18-crown-6-poly(methyl methacrylate) (PMCMA) supramolecular film, Polymer2007, 48 (8), 2425-2433.
 88. Xifei Yu, Guo Zhang*,Tongfei Shi, Yanchun Han, Lijia An, Synthesis of symmetric H-shaped block copolymer by the combination ATRP and living anionic polymerization, Polymer 2007, 48, 2489.
 89. Rubo Xing, Chunxia Luo, Zhe Wang , Yanchun Han, Dewetting of polymethyl methacrylate on the patterned elastomer substrate by solvent vapor treatment, Polymer 2007, 48 (12), 3574-3583.
 90. Junpeng Gao, Yuhan Wei, Binyao Li, Yanchun Han, Fabrication of fibril like aggregates by self-assembly of block copolymer mixtures via interpolymer hydrogen bonding, Polymer 2008, 49(9), 2354-2361.
 91. Jun Fu, Yuhan Wei, Longjian Xue, Bin Luan, Caiyuan Pan, Binyao Li, Yanchun Han, Lamella reorientation in thin films of a symmetric poly(L-lactic acid)-blockpolystyrene upon crystallization at different temperatures, Polymer2009, 50(6), 1588-1595.
 92. Junpeng Gao, Xiao Li, Binyao Li, Yanchun Han, Fabrication of polymer antireflective coatings by self-assembly of supramolecular block copolymer, Polymer 2010, 51(12), 2683-2689.
 93. Ping Yang, Xinhong Yu, Yanchun Han, Transition between crystallization and microphase separation in PS-b-PEO thin film influenced by solvent vapor selectivity, Polymer2010, 51(21), 4948-4957.
 94. Zhe Wang, Rubo Xing, Jian zhang, Jianfeng Yuan, Xinhong Yu, Yanchun Han, Micropatterning of metal films coated on polymer surfaces with epoxy mold and its application to organic field effect transistor fabrication, Appl. Phys. Lett. 2004, 85(5), 831-833.
 95. Xinhong Yu, Shunyang Yu, Zhe Wang, Dongge Ma, and Yanchun Han, Metal printing with modified polymer bonding lithography, Appl. Phys. Lett.2006, 88(26), 263517.
 96. Rubo Xing, Tengling Ye, Yan Ding, Dongge Ma, Yanchun Han, Formation of low surface energy separators with undercut structures via a full-solution process and its application in inkjet printed matrix of polymer light-emitting diodes, Org. Electron.2009, 10(2), 313-319.
 97. Jiangang Liu, Shuyan Shao, Hanfu Wang, Kui Zhao, Longjian Xue, Xiang Gao, Zhiyuan Xie, Yanchun Han*, The mechanisms for introduction of n-dodecylthiol to modify the P3HT/PCBM morphology, Org. Electron.2010, 11(5), 775-783.
 98. Zicheng Ding, Rubo Xing, Qiang Fu, Dongge Ma, Yanchun Han, Patterning of pinhole free small molecular organic light-emitting films by ink-jet printing, Org. Electron.2011, 12, 703-709.
 99. Ziyong Cheng, Daocheng Pan, HanfuWang, Maolin Pang, Yanchun Han, and Jun Lin, Fabrication of self-assembled palladium nanosheets using layered organic/inorganic hybrid as the template, Nanotechnology 2006, 17 (2), 506-511.
 100. Jun Fu, Yang Cong, Junpeng Gao, XiangYu, Caiyuan Pan, Binyao Li and Yanchun Han, Photoluminescent nanoparticles of organic-inorganic hybrids prepared by phase transfer complexation at the organic-aqueous solution interface, Nanotechnology2007,18 (2), 025704.
 101. Longjian Xue, Xiang Gao, Kui Zhao, Jiangang Liu, Xinhong Yu, and Yanchun Han*, Formation of Different Structures of Poly(3-hexylthiophene) Film on Patterned Substrate by Dip Coating from Aged Solution, Nanotechnology, 2010, 21(14), 145303.
 102. Zhe Wang, Rubo Xing, Xinhong Yu and Yanchun Han Adhesive lithography for fabricating organic electronic and ptoelectronics devices, Nanoscale 2011, 3, 2663-2678.
 103. Lidong Zheng, Jiangang Liu, Yan Ding and Yanchun Han, Morphology Evolution and Structural Transformation of Solution-Processed Methanofullerene Thin Film under Thermal Annealing, J. Phys. Chem. B.2011, 115, 8071-8077.
 104. Zicheng Ding, Rubo Xing, Lidong Zheng, Yue Sun, Xingdong Wang, Junqiao Ding, Lixiang Wang, and Yanchun Han, Self-Assembly of Carbazole-Based Dendrimers by Solvent Vapor Annealing: From Fibers to Spherulites, J. Phys. Chem. B. 2011,115: 15159-15166.
 105. Lidong Zheng and Yanchun Han*, Solvated Crystals Based on [6,6]-Phenyl-C61-butyric Acid Methyl Ester (PCBM) with the Hexagonal Structure and Their Phase Transformation, J. Phys. Chem. B. Accepted.
 106. Chuxia Luo, Rubo Xing, Zexin Zhang, Jun Fu, and Yanchun Han, Ordered droplet formation by thin polymer film dewetting on striped pattern substrate, J. Colloid. Interf. Sci.2004, 269(1), 158-163.
 107. Jianying Wang and Yanchun Han, Tuning the stop bands of inverse opal hydrogels with double network structure by controlling the solvent and pH, J. Colloid. Interf. Sci.2011, 352, 498-505.
 108. Jianying Wang, Yanchan Han, Tunable multicolor pattern and stop-band shift based on inverse opal hydrogel heterostructure, J. Colloid. Interf. Sci.2011, 357, 139-146.
获得奖励
2010吉林省科学技术进步一等奖:高分子薄膜有序图案构筑与响应功能
研究组人员概况

 

 副研究员2名,助理研究员2名

 

Tel:85262635
hfwang@ciac.jl.cn

王汉夫博士 (副研究员)
   2006-现在, 中科院长春应化所高分子物理与化学国家重点实验室,副研究员。
   2007-2008, 法国国家科学院 (CNRS) ,波尔多第一大学 (ENSCPB) ,有机聚合物实验室(LCPO),博士后。
   2004, 中国博士后科学基金,中国科学院王宽城博士后工作奖励基金
   2003, 吉林大学,理学博士学位。
   研究方向:基于分子构象基础上的嵌段共聚物自组装;有机光电功能分子的合成与自组装;光致动液晶弹形体功能薄膜
   研究成果:1. 以苯胺齐聚物嵌段共(齐)聚物为研究对象,探索研究了分子构象状态对分子自组装行为的影响规律,揭示了分子构象熵在系统自组装转变过程中的关键作用,并以此为基础,构建了含苯胺齐聚物功能结构单元在内的胶束、囊泡、纤维、纳米管等多种自组装纳米微结构,奠定了苯胺齐聚物材料功能化基础。2. 以三亚苯盘状分子为基础,利用共价键或超分子非价键力构建了以三亚苯为核心的星型盘状嵌段共(齐)聚物。通过协调三亚苯分子间π-π相互作用与外围超分子非价键力间相互作用的平衡关系,实现了分子自组装的可控性。在此基础上,探索了三亚苯/苝酸酐给体/受体超分子体异质结的构筑,获得了较大尺寸的单畴柱状相液晶体异质结薄膜,为高效率有机体异质结太阳能电池的研制奠定了实验基础。3. 探索了偶氮苯主链液晶性嵌段共聚物弹性体的制备路线,通过改变共聚单体的分子结构或长度等手段,获得了一系列溶解性较好的新型主链偶氮苯(共)聚合物,为新型光致动偶氮苯主链液晶弹性体材料的制备奠定了实验基础。
   近几年来在国内外核心学术期刊(包括Soft Matter、Macromol. Rapid Commun.、J. Chem. Phys.、Langmuir等)发表SCI研究论文20篇,获授权专利3项。完成国家自然科学基金重点项目1项,目前作为项目负责人承担国家自然科学基金青年基金1项,面上项目1项。

 

Tel:85262267
xhyu@ciac.jl.cn

于新红博士(副研究员)
   2012.01-现在,  中科院长春应化所高分子物理与化学国家重点实验室,副研究员。
   2008.07-2012.01,  中科院长春应化所高分子物理与化学国家重点实验室,助理研究员。
   2008.06,  中国科学院长春应用化学研究所,理学博士学位。
   2002.06, 湖南大学,学士学位。
   研究方向:软微加工技术和应用、聚合物薄膜凝聚态结构调控研究
   研究成果:1.结晶性嵌段共聚物的结晶与微相分离:对于结晶与微相分离之间的相互关系和作用方式的研究是实现嵌段共聚物自组装结构调控的关键因素。围绕结晶性嵌段共聚物结晶与微相分离的协同与竞争,我们主要开展了三部分工作:(1)利用原位热台研究共聚物分子量和膜厚对结晶行为的影响,分子量决定相分离强度和分子迁移速率,影响了结晶成核和相分离;膜厚改变了链迁移速度,膜厚降低,结晶缓慢,相分离驱使spinodal形貌;(2)溶剂诱导片晶与微相分离的竞争,通过溶剂蒸汽选择性影响结晶与微相分离的相互转变,提出了可溶解嵌段的自由体积增加和结晶嵌段低溶胀性分别是微相分离和结晶发生的关键因素;(3)薄膜状态下双共轭嵌段共聚物的结晶与微相分离,具有结晶性的共轭嵌段共聚物薄膜在形成过程中包括了结晶与相分离的共同作用,通过选择不同退火方式以及嵌段比例,实现了受限结晶以及结晶破坏相分离结构。2.基于界面粘附功差异的转移打印技术及应用:为解决有机光电器件中器件与器件之间的窜扰现象和湿法微加工中溶剂等对有机光电器件性能的损害,我们发展了以界面相互作用力为图案化驱动力的转移打印技术,实现了功能高分子薄膜在平面和柔性衬底上的干法图案化加工,为有机光电器件中器件软加工开辟出新技术。
   在Macromolecules,Applied Physics Letters和Polymer等SCI杂志上发表论文19篇,申请国家发明专利4项。目前作为项目负责人承担基金委青年科学基金项目一项,参加基金委“优秀国家重点实验室研究项目”一项。

 

Tel:85262267
rbxing@ciac.jl.cn

邢汝博博士(助理研究员)
   2009.07-现在,  中科院长春应化所高分子物理与化学国家重点实验室,助理研究员。
   2009.06,  中国科学院长春应用化学研究所,理学博士学位。
   2001.06, 石油大学(华东),学士学位。
   研究方向:有机光电器件微加工
   研究成果:喷墨打印被认为是在有机发光显示加工中最具应用潜力的微加工技术。针对喷墨打印图案化有机发光显示装置中存在的图案化精度低、薄膜厚度不均匀和薄膜中分子易有序聚集而严重影响器件电致发光效率等核心问题进行深入研究,获得了一些新方法,并提出了一些新理论和观点,主要内容:(1)软印刷图案化具有T型横截面的低表面能隔离柱,并用于辅助喷墨打印提高其图案化精度近一倍。(2)提出了喷墨打印有机发光薄膜均匀性与微结构协同调控的思想和溶液体系的构建原则。利用干燥过程中形成“对流搅拌”和“流动抑制”两种流动场的溶液体系,抑制引起薄膜厚度不均匀的因素并打印厚度均匀的有机发光薄膜。采用良溶剂加速干燥从热力学和动力学上抑制分子聚集的思想,制备光滑无定形的有机发光薄膜。基于以上研究结论提出构建喷墨打印薄膜均匀性与微结构可协同调控的溶液体系的原则。(3)喷墨打印有机发光小分子成膜性和抑制分子聚集。高沸点高粘度溶剂从热力学和动力学上抑制去润湿,喷墨打印制备均匀无针孔图案化有机小分子发光薄膜和电致发光器件。采用加速干燥的溶液干燥过程动力学控制,缩短溶液中有机小分子运动时间而抑制聚集,使溶液加工有机小分子发光器件效率提高近一倍。
   近年在Organic Electronics,Polymer等SCI收录的期刊上发表论文20余篇,其中影响因子大于3的13篇。申请中国发明专利6项,已授权2项。2010年获吉林省科技进步一等奖1项。目前主持国家自然科学基金委青年科学基金1项,作为主要研究人员参加科技部973项目子课题1项。

 

Tel:85262902
niitawh@ciac.jl.cn

刘剑刚博士(助理研究员)
   2011年-今,中国科学院长春应用化学研究所,高分子物理与化学国家重点实验室,助理研究员。
   2006年-2011年,中国科学院长春应用化学研究所,理学博士学位。
   2002年-2006年,吉林大学,化学学院,学士学位。
   研究方向:高分子凝聚态结构及有机薄膜太阳能电池
   研究成果:主要研究成果包括:(1)利用添加剂实现P3HT/PCBM共混体系结晶度及相分离程度的控制,指出添加剂降低了P3HT分子间的缠结程度,助于其实现线—棒转变,进行结晶;(2)通过zone-casting方法制备P3HT/PCBM体系准有序异质结太阳能电池,通过改善晶体间链接实现器件性能的提高。(3)通过控制成膜条件,实现了P3HT多晶形控制,并利用溶剂蒸汽定向挥发的方法将多晶结构应用于制备取向薄膜中;利用蒸汽辅助压印的方法将多晶结构应用于制备多级有序结构。在Organic Electronics, Langmuir等期刊上发表论文2篇。

在读研究生11人,其中博士生8人,硕士生3人
郑立东(D3),熊维(D3),孙岳(D3),丁自成(D2),徐垚卓(D2),杨华(D1),王海洋(D1),苏亚军(D1),李明光(M2),周科(M1),赵巧巧(M1)

 

郑立东(2007级)
富勒烯凝聚态结构
Tel: 13578941390
zhengld@ciac.jl.cn

熊维(2007级)
含树枝大分子的非线形嵌段共聚物的合成与形貌调控
Tel: 13843170482
wxiong@ciac.jl.cn

 

孙岳(2007级)
PCBM在共混薄膜中的扩散与聚集
Tel:0431-85262120 (15943054155)
ysun@ciac.jl.cn

 

丁自成(2008级)
咔唑共轭树枝分子聚集态结构调控
Tel:0431-85262376
dean132@ciac.jl.cn

 

徐垚卓(2008级)
刚性高分子凝聚态结构研究
Tel:0431-85262376
xuyaozhuo@ciac.jl.cn

 

杨华(2009级)
共轭嵌段共聚物结晶与微相分离
Tel:0431-85262120
yanghua@ciac.jl.cn

 

王海洋(2009级)
共轭聚合物薄膜形貌调控
Tel: 0431-85262902
hywang@ciac.jl.cn

苏亚军(2009级)
有机小分子溶液加工
Tel: 15044006350
yjsu@ciac.jl.cn 

李明光(2010级)
N型盘状液晶分子的自组装行为
Tel: 0431-85262902
mgli@ciac.jl.cn

周科(2011级)
高分子凝聚态结构及有机薄膜太阳能电池
Tel: 0431-85262902
kzhou@ciac.jl.cn

 

赵巧巧(2011级)
聚合物减反射薄膜
Tel: 0431-85262902
qqzhao@ciac.jl.cn

 
学生获奖  
1人获中国科学院50篇优秀博士学位论文;3人获得了德国洪堡研究奖学金和日本科学振兴会博士后研究奖学金;5人获中国科学院院长优秀奖和刘永龄奖学金优秀奖

部分毕业研究生去向
大学/科研院所(15人):教授/研究员(3人)、副教授/副研究员(6人)、助理研究员(2人);企业(5人);博士后(7人): 国外(6人)、国内(1人);博士(1人)

 

李学,济南大学教授
Tel:13853107626
chm_lix@ujn.edu.cn

 

张泽新,苏州大学特聘教授
Tel: 0512-69155295
zhangzx_suda@126.com

 

付俊,中国科学院宁波材料技术与工程研究所研究员
Tel:15968424387
fujun@nimte.ac.cn

 

王哲,北航副教授
wangz.jlu@gmail.com

 

朱伟平,中国神华煤制油化工有限公司研究院
zhuweiping@csdc.com

 

彭娟,复旦大学副教授
Tel:021-65643498
juanpeng@fudan.edu.cn

 

丛杨,宁波工程学院化工学院 副教授
lucycongyang@yahoo.com.cn

 

黎坚,National University of Singapore
liji@imre.a-star.edu.sg 

 

程子泳,中科院长春应化所副研究员
Tel:18686677964
zycheng@ciac.jl.cn

 

伍洋,南昌大学副教授
wuyang@ncu.edu.cn

 

崔亮,中国石油天然气集团公司
cuiliang@petrochina.com.cn

 

栾世方,中科院长春应化所副研究员
sfluan@ciac.jl.cn

 

刘林彬,山东轻工业学院副教授
Tel: 18763988232
lleebin@hotmail.com

 

黄伟欢,中国石油石油化工研究院高级工程师
Tel:010-52777277-3307
huangweihuan@petrochina.com.cn

 

张继琳,University of Cincinnati, USA
zhangjilin80@gmail.com

 

高军鹏,中国航空工业集团公司北京航空材料研究院高级工程师
Tel:15811248908
jpgao12@yahoo.cn 

 

于凯,University Of British Columbia
Thomas.kai.yu@gmail.com

 

于新红,中科院长春应化所副研究员
Tel: 0431-85262267
xhyu@ciac.jl.cn

 

罗春霞,中国石油化工股份有限公司北京化工研究院
Tel: 13699233281
chunxialuo@gmail.com

 

魏玉函,扬子石化
weiyh.yzsh@sinopec.com

 

杨平,浙江农林大学
YangPing@ntu.edu.sg

 

薛龙建,University of Osnabrueck
xlj.blueproton@gmail.com

 

赵奎,King Abdullah University of Science and Technology
chunxialuo@gmail.com

 

邢汝博,中科院长春应化所助理研究员
Tel: 85262267
rbxing@ciac.jl.cn

 

胡本慧,新加坡南洋理工大学
bhu1@e.ntu.edu.sg

 

王建颖,华中科技大学博士后
Wangjy_2002@163.com

 

李晓,University of Wisconsin-Madison, USA, 博士后
Tel: 13610742369
lixiao420@gmail.com

 

刘剑刚,中科院长春应化所助理研究员
Tel: 85262902
niitawh@ciac.jl.cn
1. 李学,2003/博士,Max-Planck-Institute for Polymer Research ,Germany,济南大学教授
2. 付俊,2004/博士,Max-Planck-Institute for Polymer Research,Germany,Massachusetts General Hospital/Harvard Medical School,中国科学院宁波材料技术与工程研究所,研究员
3. 王哲,2004/博士,日本JSPS奖学金(Kyushu University ),北航,副教授
4. 张泽新,2003/硕士,苏州大学教授
5. 彭娟,2005/博士,德国洪堡奖学金(Max-Planck-Institute for Polymer Research),复旦大学副教授
6. 程子泳,2005/博士, Max-Planck-Institute for Polymer Research,中科院长春应化所副研究员
7. 丛杨,2005/博士,University of Mainz, Germany,宁波工程学院
8. 朱伟平,2005/博士,中国神华煤制油化工有限公司研究院
9. 黎坚,2005/博士,National University of Singapore,Singapore
10. 崔亮,2006/博士,中国石油天然气集团公司
11.伍洋,2006/博士,宁波材料技术与工程研究所,南昌大学
12. 栾世方,2006/博士,威高集团/长春应化所企业博士后,中科院长春应化所副研究员
13. 刘利彬,2006/硕士,山东轻工业学院
14. 黄伟欢,2007/博士,中国石油天然气集团公司
15. 于恺,2007/博士,University of British Columbia, Canada
16. 张继琳,2007/博士,University of Cincinnati, USA
17. 高军鹏,2007/博士,中国航空工业第一集团公司
18. 于新红,2008/博士,中科院长春应化所副研究员
19. 罗春霞,2008/博士,北京化工研究院
20. 魏玉函,2008/博士,香港城市大学博士后,扬子石化
21.杨  平,2009/博士,新加坡南洋理工博士后,浙江农林大学
22.赵  奎,2009/博士,King Abdullah University of Science and Technology,阿卜杜拉国王科技大学博士后
23.薛龙建,2009/博士,RWTH Aachen University (德国洪堡奖学金)
24.邢汝博,2009/博士,中国科学院长春应用化学研究所
25.胡本慧,2009/硕士,中国航天科工集团,新加坡南洋理工大学博士
26. 王建颖,2010/博士,华中科技大学,博士后
27. 刘剑刚,2011/博士,中国科学院长春应用化学研究所
28. 李晓,2011/博士,University of Wisconsin-Madison, USA, 博士后